Lithium borate

Lithium tetraborate
Names

Other names Lithium borate
Identifiers
CAS Number	12007-60-2^Y
3D model (JSmol)	Interactive image
ChemSpider	21169645^Y
ECHA InfoCard	100.031.364
EC Number	234-514-3
PubChem CID	15764247
UNII	G5N01T5TYY^Y
CompTox Dashboard (EPA)	DTXSID20893158
InChI InChI=1S/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2+1^Y Key: PSHMSSXLYVAENJ-UHFFFAOYSA-N^Y InChI=1/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2+1 Key: PSHMSSXLYVAENJ-UHFFFAOYAA
SMILES [Li+].[Li+].O=BOB([O-])OB([O-])OB=O
Properties
Chemical formula	Li₂B₄O₇
Molar mass	169.11 g/mol
Appearance	white powder
Density	2.4 g/cm³, solid
Melting point	917 °C (1,683 °F; 1,190 K)
Solubility in water	moderately soluble
Hazards
NFPA 704 (fire diamond)	2 0 0
Safety data sheet (SDS)	External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references

Chemical compound

Lithium borate, also known as lithium tetraborate is an inorganic compound with the formula Li₂B₄O₇. A colorless solid, lithium borate is used in making glasses and ceramics.

Structure

Its structure consists of a polymeric borate backbone. The Li⁺ centers are bound to four and five oxygen ligands. Boron centers are trigonal and tetrahedral.^[1]^[2]

Lithium borate can be used in the laboratory as LB buffer for gel electrophoresis of DNA and RNA. It is also used in the borax fusion method to vitrify mineral powder specimens for analysis by WDXRF spectroscopy.^[3]

References

^ Sennova, N.; Bubnova, R.; Shepelev, Yu.; Filatov, S.; Yakovleva, O. (2007). "Li₂B₄O₇ Crystal structure in anharmonic approximation at 20, 200, 400 and 500 °C". Journal of Alloys and Compounds. 428 (1–2): 290–296. doi:10.1016/j.jallcom.2006.03.049.
^ Natalia Sennova. R. S. Bubnova; G. Cordier; B. Albert; S. K. Filatov; L. Isaenko (2008). "Temperature‐dependent Changes of the Crystal Structure of Li2B4O7". Zeitschrift für Anorganische und Allgemeine Chemie. 634 (14): 2601–2607. doi:10.1002/zaac.200800295.
^ Ron Jenkins, X-Ray Fluorescence Spectrometry, Second Edition, J. Wiley & Sons Inc., 1999, ISBN 0-471-29942-1, p 146-7.